Hi Ryan,
There are two ways to gather potential volunteer information from your website; the Volunteer Application for the Volunteer Pipeline and using WebLink forms.
You can only specify questions asked to the volunteer's references using the Volunteer Application. When using the volunteer application, pay special attention to the Volunteer Opportunities Requirements panel. Check off the reference check requirement. This will give you an option to write any specific questions you would like your volunteer coordinator to ask the potential volunteer's references. You can ask them about skills and demeanor, etc..
If you want the applicant to answer questions themselves, you can do so through a WebLink form. Create the question in the Questions Panel. I would recommend adding yourself or volunteer coordinator to the Cc line or Bcc line of the Confirmation message so you are notified whenever someone fills this out. If you use the WebLink form, the candidate will not be entered into the Volunteer Pipeline automatically.
Please reply for any clarification -
Serving Him with you,
Marie Armitage